Chemical sciences

The life cycle of hydrotreatment catalysts: from active phase genesis to catalyst recycling Catalysts are essential products for numerous industrial processes, including the hydrotreatment of oil feeds or bio-based feeds. Their properties stem from the active metal materials they contain, the value and criticality of which justify efforts to recover them from waste products. Accordingly, as a major producer of catalysts, one of IFPEN group’s key priorities is to apply the principles of the circular economy to them.

The photocatalytic reduction of CO2 to “C1/C2 solar fuels” is an attractive conversion reaction since it has the advantage of eliminating this greenhouse gas while providing a usable product. However, despite extensive research efforts, the level of CO2 conversion remains very low, even for the most active catalysts on the market, and the reaction mechanisms involved is still poorly understood. In order to remedy this, this PhD research focused on the study of a model Pt/TiO2-type photocatalytic system. For the purpose of the study, an operando methodology was deployed combining several techniques...

Heterogeneous catalysts are materials that make chemically possible and economically viable countless industrial processes in the service of energy-related and environmental problems, such as fuel production and air quality (vehicle emissions, building interiors). Their implementation involves two major scientific challenges: (1) the identification of the chemical, structural and morphological properties of an optimal catalyst , (2) the evolution of these properties over the catalyst’s life-cycle (synthesis, preparation, use, recycling)...

Driven by the global challenge of switching to a more sustainable economic and energy model, IFPEN has been studying for a number of years biosourced products with high added value and working to develop processes for biomass recovery, as an alternative to conventional petrochemistry.

Although the climate crisis makes the reduction of CO2 emissions a matter of urgency, some industries will have difficulty in avoiding them, such as cement plants (where the core process is currently based on the calcination of CaCO3) or refineries, which are currently highly energy-intensive. Hence the huge potential interest in procedures that could capture the CO2 released directly from the plant (...) then recover it at a fraction of the energy cost...

Faced with the current climate challenges, alternative fuels are attracting a growing interest for the mobility of the future. Of the various possible alternatives, hydrocarbons could be synthesised via a well-known process: the Fischer-Tropsch (FT) process, based on Syngas (CO and H2) produced, in particular, by biomass gasification. (...) However, the deactivation of FT catalysts is a major issue that directly impacts the costs of the process. (...) To identify these mechanisms, a multiple-stage methodology was implemented as part of a doctoral thesis...

The production of biofuels, renewable diesel or sustainable aviation fuel can be achieved through lipid feedstocks conversion, such as vegetable oils, used cooking oils or animal fats. Through a hydrotreatment stage, we obtain long-chain normal paraffinsa, which must then be isomerised or cracked in order to adjust the properties of the effluent, resulting in the specifications required according to the targeted fuel type (particularly cold flow properties and/or final distillation temperature)...