Physical chemistry

Solid-state lithium (Li) batteries offer the promise of surpassing the energy density limits of current generations of Li-ion batteries, while being safer. The key to these performances lies in the choice of the solid electrolyte (SE) and its integration into the electrochemical cell. Among the various SEs studied, inorganic thiophosphate phases (Li₃PS₄ and Li₆PS₅X with X = Cl, Br, I) are notable for their high ionic conductivity at room temperature (> 10⁻⁴ S.cm⁻¹), which makes them suitable for use as solid electrolytes.

Heterogeneous catalysts are materials that make chemically possible and economically viable countless industrial processes in the service of energy-related and environmental problems, such as fuel production and air quality (vehicle emissions, building interiors). Their implementation involves two major scientific challenges: (1) the identification of the chemical, structural and morphological properties of an optimal catalyst , (2) the evolution of these properties over the catalyst’s life-cycle (synthesis, preparation, use, recycling)...

Although the climate crisis makes the reduction of CO2 emissions a matter of urgency, some industries will have difficulty in avoiding them, such as cement plants (where the core process is currently based on the calcination of CaCO3) or refineries, which are currently highly energy-intensive. Hence the huge potential interest in procedures that could capture the CO2 released directly from the plant (...) then recover it at a fraction of the energy cost...

The increase in the level of atmoshpheric CO2 and the resulting climate change are a global concern. Despite this, the use of fossil fuels continues to grow, in response to high energy demand. Combined with storage and CO2 conversion solutions, Chemical Looping Combustion processes (CLC) offer a medium-term solution to reducing the impact of energy production from fossil fuels, or even biomass...

The transport of colloidal particles in porous media is relevant to a number of fields, including geosciences and environmental engineering. Particle-matrix interactions can lead to deposit formation and accumulation, potentially damaging the medium and altering its permeability. (...) At IFPEN, the problem was originally studied for oil and gas production, but research has now been extended to include the fields of geothermal energy and geological storage of CO2.

The design of high-quality porous materials is a major challenge for the energy efficiency of industrial processes in the fields of catalysis and biocatalysis and separation and purification operations. For such applications, these materials derive their properties of interest from their specific microstructure, incorporating a large quantity of empty spaces that are organized and connected on a nanometric scale. IFPEN and Saint Gobain Research Provence (SGRP) joined forces to acquire a tool that will ultimately facilitate the development of porous materials optimized for given usages.